![]() ![]() Only time it ever fails me is if it falls (at my fault), if another app overrides it (can’t help it), or if I just forget to open the app before bed. Overall, great loud alarm app with great features. The name of the app helped me find it a lot easier, definitely happy about that. Being able to change the theme, background, and design color for free was an added bonus, other Alarm apps usually make that a purchasable feature, so not being forced to fall asleep to a mini flashlight I couldn’t avoid was nice. Giving review and sending feed back both give you espresso too, but that’s just a normal app growth thing and you’re never constantly harassed by the app asking for a review so its ok. The “Espresso” system is one of my favorite parts, you don’t need to actually spend money to get them, its more of a reward system, get some for setting the first alarm, then a little bit each day for using the app and getting up to the alarms. I sleep through a lot of alarms and am a pretty heavy sleeper, but these alarms can actually get me up and moving. Bombard your eardrums every peaceful morning by placing the Sonic Bomb ultra loud alarm clock on your nightstand It. Wake up!! I’m telling everyone about this app and whoever created this, thank you is a absolute understatement. Now granted this alarm wakes up the entire house, but I truly don’t care at this point. Doing regiments, taking meds, and still no results. I’ve been to sleep studies and bought so many different alarms and nothing helped. How can you just tell your job, I CANT WAKE UP, but hey Sorry for being late. My military career in the Air Force was nearly ruined because of this. I also conditioned my children to do the same thing, and it’s very sad in the morning waking up, knowing I’m failing them because they keep missing school and I’m too embarrassed to walk them in the school at 10am, almost during lunch time. I’ve even been scared to commit to jobs or events because i knew I couldn’t wake up. I have lost jobs, been put on suspension, written up, talked about, missed so many appointments and opportunities. I have suffered from not being able to wake up for over 10 years. Email us at Tweet us at Like us on Facebook!īy downloading this app, you accept the Terms of Service and Privacy Policy agreements."I love this app! Especially when you keep snoozing it, because then it says you can't snooze anymore and you have to get up!" grace55667 Extra-loud alarm clock ideal for those with hearing difficulties Large display clock make digits easier to read Can can continuously adjusted to over 95dB."This app is so cool, the features are awesome and it's FREE!!!" Maemaepdx. ![]() You get to talk to it and it talks back." Jessie_baee "I've been waiting foreverrr for a great app like this.◉ Beautiful, customizable alarm clock design ◉ Get fun voices like Stewie and Hermione that motivate you to wake up if you keep snoozing! ◉ Set a time at which you can't snooze anymore! ◉ Say “Jarvis light” to turn on the flashlight. ◉ Say “Jarvis set alarm for 7:30 AM” to set an alarm ◉ Select from the built in beautiful backgrounds. ◉ Add your own background from your photos or camera or choose from dozens of beautiful designs Complete with ground shaking super-charged bed shaker, and turbo-charged 113dB extra loud alarm.◉ Play random sounds each morning so you can't get used to it The Stealth grey color with red controls, night vision display, and pulsating alert lights won’t keep you in the dark. This clock gets anyone out of bed so no matter the occasion if waking up on time is a must, take a look at the Sonic Bomb Loud Alarm Clock. The new Sonic Bomb SBB500ss AKA “The Bomb”, has been designed for guys of all ages on a mission. The Sonic Bomb Loud Alarm Clock comes from the Sonic Boom family of loud vibrating alarm clocks. This clocks dares you to sleep through it’s alarm! Hearing Aid Protection Hearing Aid Protection. ![]()
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![]() ![]() The Psychedelic 60’s: Literary Tradition and Social Chang eĪn online exhibition from the University of Virginia’s Special Collections Library. “The Process” contains an interactive exploration of how a poster is printed using offset lithography. The Smithsonian American Art Museum’s online exhibition of American posters from the 1930s to the 1990s, which explores the strategies of commerce, propaganda, and patriotism. PBS Summer of LoveĪ website with resources related to the 2007 PBS documentary, Summer of Love, including video clips and a teachers guide. The artist’s website has biographic information as well as images of his work. Wes Wilson: Official Website of an American Artist There is also information about the San Francisco Sound playlist available through iTunes. You can access images of other posters as well as information about the artists and culture of the psychedelic scene. ![]() The Denver Art Museum’s website accompanying the exhibition, "The Psychedelic Experience: Rock Posters from the San Francisco Bay Area, 1965–71," on view from March 21-July 19, 2009. Audio Tracks from Bands Listed on the Poster Websites The Psychedelic Experience His designs set the style, capturing the full sensory experience of the dancehall environment and the visual distortions brought on by psychedelic drugs.įootage of Quicksilver Messenger Service, a band listed on the poster, performing the song "All I Ever Wanted to Do" at the Monterey Pop Festival in 1967. And some of them were pretty weird, pretty strange," said Wilson. "I imagine the posters were like some kind of imprint like a section of my mind at that time. Wilson was a part of the counter-culture that he was trying to reach out to, and was inspired by his personal experiences. But I soon learned that a stolen poster carried home and pasted on a refrigerator reached the audience I wanted," said Helms. "It was very disconcerting to poster a whole street and then walk back a few minutes later and discover that 90 percent had been removed. Posters were plastered on telephone poles and in store windows, and were often stolen by people who took them home to hang on their walls or refrigerators. The movement, colors, and images all reflect the kinds of things that would appeal to a concertgoer's many senses. Designs for concert posters were a visual reflection of the experiences one might have at a dance concert. The term "psychedelic" comes from the Greek psyche (mind) and deloun (make visible or reveal), and refers to the mind-altering effects of LSD, a hallucinogenic drug that was frequently used at these events. Psychedelic posters were originally created as advertisements for dance concerts that took place in San Francisco from 1965 to 1971. Today he creates artworks from his farm in the Missouri Ozarks. Wilson continued to produce posters for other venues, including the Avalon Ballroom. ![]() Although Graham was building an increasingly profitable poster-selling enterprise, Wilson was paid only $100 per poster, without royalties. He liked that I could do posters without him having to tell me anything." Despite the freedom that came with working for Graham, Wilson began to feel exploited and stopped producing posters for the Fillmore in 1967. "Chet almost always had the theme already picked out, but with Bill, you could do your own thing, mainly because he was too busy to deal with you. While Chet Helms loved to contribute to the poster-making process, Graham allowed Wilson the artistic freedom he desired. In 1966, when the pressure of designing multiple posters each week became overwhelming, he began working solely for Bill Graham. Wilson initially produced as many as six posters a month for the Fillmore and the Avalon. One of the first projects to bring Wilson recognition was a handbill for the legendary Trips Festival, a three-day event that took place in San Francisco and set the stage for later dance concerts. During the 1960s, he became the first artist to consistently create posters for the two main concert promoters on the San Francisco music scene-Bill Graham, who produced concerts at the Fillmore Auditorium and Chet Helms, who ran the Avalon Ballroom. He got his start while working for a print shop in San Francisco, where he designed posters and handbills for early dance concerts. Wes Wilson was born in Sacramento, California in 1937. ![]() ![]() ![]() In infant rats taurine was also found to significantly increase estrogen (E) concentrations, but in adult and aged rats no significant rise in E was observed. Specifically when male rats were provided taurine, the hormones testosterone and luteinizing hormone (LH) were significantly increased across all age groups. Effects of taurine on male reproduction in rats of different ages.Ī recent rat study out of China explored the role of the beta amino acid taurine in male sexual function and noted a striking correlation. On to the naughty bits! Taurine Is For Lovers More on that later in the meantime, think about cutting it off after this glass. Oh, and one more thing: If you're pregnant, stay calm. Unfortunately, it didn't help the keyboard you just spilled it across. That glass of red wine in your hand can help your sex drive, your metabolism, and even your physique (not to mention the appearance of your partner). In fact, I bring you news that you definitely want. So in this installment, I'll look at current studies involving supplements that could help you raise your natural levels of testosterone, how some natural supplements match up to a certain blue pill, and name a few things to avoid unless you want your T-level to sink faster than a shanked nine-iron.ĭon't worry, ladies, I haven't forgotten about you. I believe in giving the people what they want. Peruse the ads in a golf magazine these days, and you'll see the letter T more often than you'll see the word "tee." The topic of raising male testosterone levels is sure to bring a crowd to stiff attention, whether it's the world of sports nutrition and performance, or poolside at a senior center. (Cue the Sesame Street theme.) This installment of Research Roundup is brought to you by the letter T. ![]() ![]() Yes– it’s totally edible when cooked properly. Lastly, I know you want to ask me about the skin. ![]() Acorn squash is full of fiber and magnesium, which are two things I’m always looking to get more of in my diet. Plain old green beans and asparagus are just not exciting anymore! I like that this parmesan acorn squash is a little different, and makes me feel proud that I’m still eating a good vegetable. Side dishes are always a hard one for me to find. It helps balance out the sweet notes of the squash, and in my option, makes it taste WAY better than it’s sweeter recipe counterparts. The parmesan adds a salty and nutty flavor, along with a nice brown crust on top. When researching about acorn squash, I noticed that all of the recipes were sweet, playing on the natural sugars… I, on the other hand, wanted to try something savory. I saw a picture of this unique shape in a magazine and I knew I had to try it. ![]() I think that’s what first drew me to wanting to make these. They’re a gorgeous accompaniment to your favorite chicken recipe, and even taste great topping a fall inspired salad. Okay, look at the shape of these things, like little decorative flowers. My roasty toasty parmesan acorn squash is not only cute, but really delicious. ![]() If you feel this way too, then you might really enjoy this recipe. It’s too sweet to be considered savory, and the texture is too mushy to enjoy more than a few bites. All squash haters unite! I will be the first to say I’m not a fan of squash. ![]() ![]() Before it looked like this:Īdding this to. But why has the coloring of my been removed? And I would also expect that the branch name should be colored. # should be on the output of commands, not on the prompt # off by default to not distract the user: the focus in a terminal window Create New Git Branch From Current Branch The easiest and most popular way of creating a Git branch is: git checkout -b This creates a new branch from the current branch. Based on the above I now have the below in my ~/.bashrc file: # uncomment for a colored prompt, if the terminal has the capability turned To switch Git branches, enter the following command: git checkout Note: Instead of type the name for the new branch. Switching branches is pretty simple and Git provides us with the Git Checkout command and the Git Switch command to change branches. This can be faster if you have a lot of files on other branches you don't care about.I am using this guide to show the branch name in gnome terminal (Ubuntu 15.10) when working in a git repository. With Git 2.23 (August 2019) and the new command git switch: git switch -f .The second, using the -single-branch flag, will only fetch updates that pertain to the branch being downloaded. The first will clone the entire repo, and checkout the dev branch. The new branch's history will start at the current place of the branch you 'branched off of. This will create a new branch off of the current branch. You can even checkout commits and enter detached head mode, but that is a more complex topic. Checkout is what allows you to swap between branches. git checkout BRANCHNAME git pull origin BRANCHNAME. You can change this with some flags, usually done in one of two ways: To create a new branch in Git, you use the git checkout command and pass the -b flag with a name. Run the following to get a remote branch. Meet Bhalodiya Jan 3 at 7:38 Add a comment 13 Answers Sorted by: 393 If anotherbranch already exists locally and you are not on this branch, then git checkout anotherbranch switches to the branch. Again git checkout branch-name is still supported and working. If you take this URL, and run git clone, it will download the default branch, usually master. 1 here is the quick answer git switch branch-name it is a new way of doing it. It does not tell you how you should download it. Once created you can then use git checkout newbranch to switch to that branch. When you want to start a new feature, you create a new branch off main using git branch newbranch. ![]() The git branch command can be used to create a new branch. The idea behind this move is to let people use git switch for switching branches and git restore for undoing changes from a commit. This is because, even if you're switched to a branch on the website, Github only gives you the URL to download the repo from. New Branches Git checkout works hand-in-hand with git branch. You may have tried this only to find that you accidentally downloaded the master branch. You'll want to clone the branch using the git clone command. ![]() However, downloading as a zip has a lot of downsides, and breaks Git history. ![]() ![]() ![]() You need training if you’re going to be a concealed carrier. If it’s good for concealed carry, it’s good for target practice too. You can’t expect much more from a weapon of this type. In fact, it may even do a good job at 30 yards. Don’t expect to have this weapon serviced many times.Īnd you can bet that this revolver will deliver accurate shots from 25 yards out. Shooting it hundreds of times will not break or jam it and neither will dropping it. The Ruger SP-101® is very durable and resilient. The grip is amazing, such that rain or sweaty palms shouldn’t affect your precision too much. It allows tight handling and makes sure that you’re always shooting straight ahead. We can thank the grip for the accuracy of the SP-101®. This is why people prefer this gun when it comes to safety. It does pack a punch, though, as it delivers a solid amount of firing power. This one is widely used by concealed carriers. That said, some people are looking for firepower, so think about what you need. Remember, for personal protection, you’re not looking for firepower but safety. If you’re 5’3” and weigh barely 140 lbs, a heavy gun will be hard to wield, conceal, and operate. You need to consider how heavy a weapon is and your own size. However, this isn’t necessarily the case. Usually, the bigger a weapon is, the heavier it will be. When picking the best 9mm revolver for you, you may want to consider its size. (People may not have any warning if it’s concealed.) But if a revolver is too large, it’s going to stick out like a sore thumb. In most states, you’re going to need a concealed carry license to carry a hidden firearm. It’s nobody’s business what you’re carrying, as long as what you’re doing is legal. You’re probably planning on using it as a concealed carry. You’ll keep it somewhere hidden, anyway.īut if you plan on carrying the revolver on you, you need to consider its size. Want to keep a gun inside your home to ward off burglars and intruders? Then the size doesn’t really matter. Any accuracy statistics that are further away won’t tell you too much about the revolver. Within that range, feel free to compare different revolvers and their accuracy. The range is lower, the barrel is shorter, and you won’t have any aiming paraphernalia, unless your role model is the mid-90s Danny Glover.Įxpect effective accuracy at up to 25 yards. Yes, this is true, but with pistols and revolvers, you can’t expect rifle- or carbine-grade accuracy. AccuracyĪccuracy is an important factor in firearms. Unfortunately, there is not much you can do here than to listen to what the other users have to say. Remember, we may be talking about life-and-death situations here. The fact that a weapon is constructed of the best materials on the planet won’t mean anything if a revolver jams on you when it’s supposed to fire. A firearm needs to be able to take quite a bit of abuse. The best 9mm revolver will be built of quality materials, such as steel, aluminum, or polymer. This is often affected by the price, but there are pricey models that have poor builds too. Give a little more to receive a little more. After all, any revolver is a deadly weapon – you don’t want to run the risk of misfiring. However, if you’re like most people who are looking to protect themselves, their families, and their homes, the price is going to be an important factor.Īs a rule of thumb, quality, performance, and durability are much more important factors than the price. You can skip this part if that’s the case. For some, the price tag won’t matter too much. Of course, no one can ignore the importance of this factor. So, if you’re looking at high-capacity firearms, you’re best off looking elsewhere. ![]() In some rare cases, you’ll find it that they can fit up to 10 rounds in one go. If you want to protect yourself from big game and criminals, you’re much better off getting a bigger-caliber rifle. Be that as it may, a 9mm revolver won’t stop a bear in its tracks. After all, the standard-issue police weapons are often 9mm in caliber. Some may perfectly fit your pocket others will require a holster.ĩmm revolvers pack a punch. 9mm revolvers are perfect if you want to practice concealed carry (EDC – everyday carry). Know What You’re Looking forĪlthough revolvers, especially 9mm, aren’t really pocket-tearing cannons, they aren’t packs of gums either. After years of searching, not only have I found my perfect match, but I am now prepared to help you do the same. I’ve spent years trying to find that perfect revolver. If you don’t know what you’re looking for either, you’ve come to the right place. Sure, they may help you, but they don’t know what you are looking for. Neither is it about going to the official firearms distributor. It’s not just about going to the local pawnshop and asking around. To find the 9mm revolver that perfectly suits you, you need to take multiple things into consideration. ![]() ![]() ![]() Adobe Photoshop CS6 only strengthens the benchmark softwares existing position. In this case, the contract will automatically renew every month, but should you choose to cancel (we explain how to cancel below) you will be able to use Photoshop until the end of that month, at which point your contract will cease. By Adobe Systems Free to try Editors Rating. This is why the best option, in this case, is to sign up for a month-to-month contract. Since then, the software has become the most used tool for professional digital art, especially in raster graphics editing. This is a slightly better scenario than if you were paying annually – in that case, your contract will continue to the end of the term. Basically, if you sign up for the cheaper ‘annual contract, paid monthly’ and then choose to end your subscription you will be able to do so, but if you end the contract after the first 14 days “you’ll be charged a lump sum amount of 50% of your remaining contract obligation and your service will continue until the end of that month’s billing period.” Latest Version Overview Professional Photo, Image Editing Software Photoshop Painting Incomparable Graphic Software Photo Editing Lots of functions. Photoshop with 100GB of cloud storageĪdobe explains the legal terms of the various contracts here.
![]() The lateral overlap of the atomic orbitals that are aligned perpendicular to the internuclear axis forms a pi bond, thus the extent of orbital overlapping in a sideways manner is smaller.Īs a result, the sigma ( σ ) bond is more powerful than the Pi ( π) bond. The pi bond is a covalent connection created by the lateral overlapping of half-filled atomic orbitals of atoms. The sigma bond is a covalent link produced by the head-on overlapping atomic orbitals. Differences between sigma bonds and pi bonds.Similarities between sigma bonds and pi bonds.Practice: Determine the number of sigma and pi bonds. P orbitals are orthogonal to one another which prevents the formation of pi bonds between each to the same atom. In addition, in order to rotate an atom about a double bond, the pi bonds must break first. This means that the third of the p orbitals is parallel to a given sigma bond and thus the atom will require invoking the d orbital in order to form quadruple bonds. As you can tell from the picture, only 2 of the 3 p orbitals can be perpendicular to the σ bond. Unlike normal sigma bonds which can freely rotate, the addition of pi bonds prevents a bond from rotating. It is important to note that their orientation is orthogonal, as well as being displaced somewhat, to the initial sigma bond and parallel to the p orbital of the other atom. The overlapping of un-hybridized filled p orbitals form π bonds. The different possible orientations (before pi bond formation) are also called “rotamers”, though sometimes they go by the name “ geometric isomers“. ![]() This means that the groups attached to the atoms participating in the pi bond have a constant relative orientation. Due to the displacement of the pi electron cloud, any change in orientation between the atoms decreases orbital overlap. However, once a pi bond forms between two atoms, all free rotation ceases. Ethane has free rotation around its pi bond, allowing for an infinite number of rotamers. Often this rotation can occur very rapidly ethane, for instance, completes 10 10 full rotations around its C-C bond per second. Chemists call the different orientations these atoms can have with respect to one another rotamers, which have a lot of importance in organic chemistry. Single bonds allow this because they only have one bond, a sigma bond, which connects the two nuclei precisely along their axis. This means that each atom in a single bond can rotate independent of one another. Specifically, single bonds allow for free rotation around the axis of the two nuclei. This has important ramifications for molecule in question with pi bonds. ![]() Pi Bonds and RotamersĪs you may notice, pi bonds form combined electron clouds that are a little displaced from the axis between the two nuclei. Referring to a molecule like diatomic nitrogen, the formation of N 2 would need 1 sigma and 2 pi bonds between the two nitrogen atoms to satisfy the triple bond. Thus to conclude, single bonds between atoms have a sigma bond any additional bonds between the two atoms are pi bonds double bonds have 1 sigma and 1 pi bond and triple bonds have 1 sigma and 2 pi bonds. Once this orbital is filled, the bond between the 2 atoms breaks. This bonding will also create an anti bonding orbital. This occurs when the un-hybridized (filled) p orbitals of each respective atom overlap to form a higher electron density between the two atoms outside of the established sigma bond. Different sigma and pi bond combinationsĪny additional bonds between two atoms are explained with the formation of pi bonds. ![]() The constructive interaction will thus lead to the formation of a sigma bond between the two atoms with a higher electron density shared between the two nuclei. Sigma bonds form when the available orbital with the highest energy of each atom overlaps one another. ![]() To start, we must explain both bonds: Sigma(σ) and Pi(π). Sigma and pi bonds are an aspect of valence bond theory and molecular orbital theory that explains the existence of double and triple bonds. You’ll also have the opportunity to apply what you know with some worked examples. In this article, you will learn about the basics of sigma and pi bonds and their importance to organic chemistry. ![]() ![]() ![]() The graphic below illustrates the result of intersecting two polygon feature classes with the Output Type parameter set to LINE. The output polygon features are where a polygon from one of the input feature classes or layer intersects a polygon from the other input feature class or layer. The graphic below illustrates the result of intersecting two polygon feature classes with the Output Type parameter set to either POLY or the default (LOWEST). Touch at a point-This type of intersection can be produced by specifying POINT as the Output Type.Common boundary/touch at a line-This type of intersection can be produced by specifying LINE as the Output Type.Overlap-Area of overlap can be produced by leaving the Output Type to its default value (LOWEST). ![]() This can be useful to discover polygon overlap and line intersections (as points or lines). In this case, instead of discovering intersections between the features from the different feature classes or layers, it will discover the intersections between features within the single input. These are not a different representation of the same intersections they are intersections that can only be represented by that geometry type (point, line, or polygon). Specifying different output type will produce different types of intersections of the input feature classes. The output geometry type can only be of the same geometry or a geometry of lower dimension as the input feature class with the lowest dimension geometry (point = 0 dimension, line = 1 dimension, and poly = 2 dimension). The inputs can be any combination of geometry types (point, multipoint, line, or polygon). To explicitly control the output spatial reference (coordinate system and domains), override the default spatial reference properties using the appropriate geoprocessing environments. When multiple feature classes or layers are specified in the list of input features, the order of the entries in the list does not affect the output feature type, but the spatial reference of the top entry on the tool dialog box (the first entry in scripting) in the list will be used during processing and set to the output. Writes these intersections as features (point, line, or polygon) to the output.Discovers geometric relationships (intersections) between features from all the feature classes or layers.Cracking inserts vertices at the intersection of feature edges clustering snaps together vertices that are within the xy tolerance. All the input features are projected into this spatial reference for processing. For details on how this is done, see Spatial reference and geoprocesssing. This will also be the spatial reference of the output feature class. Determines the spatial reference for processing.The features, or portion of features, that are common to all inputs (that is, they intersect) will be written to the output feature class. The Intersect tool calculates the geometric intersection of any number of feature classes and feature layers. ![]() ![]() Pure Dragon's double version is Double Pure Dragon.His beard grows longer as he gets older.imagine a creature so pure that it almost makes you blind with the light of its pureness?. This was originally intended for the Eternal Dragon. Dragon City Wiki is a FANDOM Games Community. Pure Terra: 1 or Dragon Black Market 27 November 2012 - 30 November 2012 2,000 : 1 day 20 hours 384k 384k: Pure Flame: 1. ![]() The new design for the Pure Dragon is proof. Pure Elemental Hybrids can either be purchased for large amounts of gems or bred by breeding a Pure with a basic Elemental. For unknown reasons they changed their mind on this. ![]() They intended to release another new element named Eternal. BASE MOVES These are the moves that Paladin Dragon will know upon hatching. You can however collect Paladin Dragon orbs from chests and events Future events may also come up that allow you to win the Paladin Dragon. Did you know - SP originally had another name for the new Legend icon. 97 Category: 2 How to breed the Paladin Dragon The Paladin Dragon is not breedable.This makes the Pure the only Dragon that has only two Trainable Attacks. This dragon can learn Pure Light Attack only once, although the option shown twice.Pure dragon has the highest hatching time out of all the elemental dragons.After the Light and War update, breeding two pure dragons or two Pure Hybrids can result in Legendary Dragons.After the update, all Pure Elemental habitats replaced with normal Pure Habitats.Pure Dragons do not enjoy this boost, because there are no Pure Crystals as of yet. Biakkan seekor Pure Dragon level 15 ke atas dengan seekor Terra Dragon level 15 ke atas untuk mendapatkan Ivory Dragon. Elemental Crystals now boost Pure Hybrid earning. Ada tiga naga spesial dalam permainan ini yang bisa dibiakkan oleh naga Pure.For example, you can place Pure Terra inside Terra Habitat. Now you can place Pure Hybrids inside Elemental Habitats.Later, After Primal Element was introduced, Pure Element is now weak against Primal Hybrids. Now this element had been re-designated to pure attacks, which are critical damage against Legend Hybrids. It was also dealt weak damage to Pure Element by itself each other. The Pure element was, originally, the only element to have no weaknesses against any element or deal strong damage against them. ![]()
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